SnAgCu无铅焊膏用活性剂的优选研究

    Optimization of Active Agent for Sn AgCu Lead-free Solder Paste

    • 摘要: 开发了一种新型SnAgCu无铅焊锡膏用助焊剂,研究助焊剂中活性剂成分及含量对焊锡膏润湿性和焊点腐蚀性的影响。根据焊点形貌及铺展率,对9种有机酸活性剂进行初步优选,并进一步以铺展率、焊点形貌、焊后残留物以及焊点腐蚀作为主要评价指标,研究优选的3种有机酸含量与铺展率、焊点形貌及腐蚀关系的内在联系。设计正交试验,选取合适的因素水平,进一步对优选的有机酸进行复配,结合极差分析确定助焊剂中活性剂的最佳配比。结果表明:有机酸复配不仅提高焊点铺展率、改善焊点回缩,还能减轻焊点腐蚀,当助焊剂中A酸、己二酸和丁二酸的质量比为2.5∶4.0∶2.5时,配制的Sn3.0Ag0.5Cu(SAC305)无铅焊膏具有优良的润湿性,焊锡膏铺展率达到85.13%,焊点无回缩,焊后残留物少,焊点腐蚀小。

       

      Abstract: A new type of flux for SnAgCu lead-free solder paste was developed. The effects of composition and content of active agent in the flux on the wettability of the flux and the corrosion of the solder joint were studied. Nine organic acid surfactants were preliminarily optimized according to the morphology and spreading rate of the solder joints,and the internal relationships between the content of the three optimized organic acids and the spreading rate, morphology and corrosion of the solder joints were further studied with the spreading rate, morphology of the solder joints, residuals after welding and solder joint corrosion as the main evaluation indexes. The orthogonal experiment was designed and appropriate factor and level were selected to further compound the preferred organic acids, and the best ratio of active agents in the soldering flux was determined combined with range analysis. The results show that the combination of organic acids not only improves the spread rate and shrinkage of solder joints, but also reduces the corrosion of solder joints. When the mass ratio of A acid, adipic acid and succinic acid in flux is 2.5 ∶4.0 ∶2.5, the prepared Sn3.0Ag0.5 Cu(SAC305) lead-free solder paste has excellent wettability, the spread rate of the flux is 85.13%, the solder joint has no retraction, there are few residues after welding, and the corrosion of the solder joint is small.

       

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