Ti含量对VCrFeTiTa高熵合金组织和硬度的影响

    Effect of Ti Content on Microstructure and Hardness of VCrFeTiTa High-entropy Alloy

    • 摘要: 通过真空悬浮熔炼方法设计并制备了5种VCrFeTixTa0.2x=0.2, 0.4, 0.6, 0.8, 1.0)系列高熵合金,通过X射线衍射仪(XRD)、扫描电子显微镜(SEM)、能谱分析仪(EDS)和维氏显微硬度计,探讨了不同Ti含量对VCrFeTixTa0.2系列高熵合金组织和硬度的影响。结果表明:5种高熵合金均包含BCC1相和BCC2相,BCC1相富集Cr和V两种元素,而BCC2相富集Fe、Ti和Ta三种元素。5种高熵合金经1000℃保温3 h,水冷淬火后,晶粒发生了明显细化。同时,BCC1相所占比例明显增加,元素分布更加均匀,更倾向于形成单一的固溶体结构。各试样的原子半径δ值随着Ti含量的增加而逐渐增大,硬度也随之增大。热处理后,由于发生了固溶强化,形成了更多的单相固溶体,使得高熵合金的硬度进一步提高。

       

      Abstract: Five VCrFeTixTa0.2x=0.2, 0.4, 0.6, 0.8, 1.0) series high-entropy alloys were designed and prepared by vacuum suspension melting technology. By X-ray diffract meter(XRD), scanning electron microscope(SEM), energy dispersive analyzer(EDS) and Vickers micro-hardness tester, the effects of different Ti contents on the microstructure and hardness of VCrFeTixTa0.2series HEA were discussed. The results show that the five kinds of HEA contain BCC1 phase and BCC2 phase.The BCC1 phase contains more Cr and V, while the BCC2 phase contains more Fe, Ti and Ta. When the five kinds of HEA are kept at 1000 ℃ for 3 h, the grains are obviously refined after water-cooling and quenching. At the same time, the proportion of BCC1 phase increases significantly, the element distribution is more uniform, and it is more inclined to form a single solid solution structure. The atomic radius difference δ value of each sample increases gradually with the increase of Ti content, and the hardness also increases. After heat treatment, due to the formation of more single-phase solid solution and the occurrence of solid solution strengthening, the hardness of the high-entropy alloy is further improved.

       

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