钛合金表面二氧化锆/羟基磷灰石涂层的制备及性能研究

    Research on Preparation and Properties of Zirconia/hydroxyapatite Coating on Titanium Alloy Surface

    • 摘要: 为了提高TC4钛合金的耐腐蚀性,并提高涂层之间的结合力,采用水热-电沉积方法,在不同沉积电流密度下,在钛合金基体上制备二氧化锆/羟基磷灰石复合涂层。通过电子扫描电镜和X射线衍射仪表征了不同工艺下涂层的微观形貌和相组成。利用划痕法和电化学测量考察了基体和不同复合涂层的结合强度和耐腐蚀性。用接触角测试仪评估了基体和涂层的浸润性。结果表明,当电流密度为-2 mA时,涂层结晶度和结合强度最高。在人体模拟液中表现出了最好的耐腐蚀性,自腐蚀电流和腐蚀电位分别为2.78×10-9 A·cm-2和-470.75 mV,与基体相比,提高了两个数量级。阻抗(EIS)测试表明,用-2 mA制备的复合涂层具有更好的电化学特性。二氧化锆改善了基体和羟基磷灰石涂层的结合力,在电流密度为-2 mA工艺下制备的复合涂层,具备较高的结晶度和结合强度,其耐腐蚀性均优于其他工艺和基体。

       

      Abstract: To improve the corrosion resistance of TC4 titanium alloy and enhance the bonding between the coatings,Zirconium dioxide/hydroxyapatite composite coatings were prepared on titanium alloy substrates by hydrothermal-electrode position method at different deposition current densities. The microscopic morphology and phase composition of the coatings under different processes were characterized by electron scanning electron microscopy SEM and X-ray diffractometer XRD. The bond strength and corrosion resistance of the substrate and different composite coatings were investigated using scratch method and electrochemical measurements. The wettability of the matrix and coatings was evaluated using a contact angle tester. The results show that the coating crystallinity and bond strength are highest at a current density of -2 mA. The best corrosion res istance is demonstrated in human body simulating fluid with self-corrosion current and corrosion potential of 2.78×10-9 A·cm-2 and -470.75 mV, respectively, which is two orders of magnitude higher compared to the substrate, and the impedance(EIS) test shows that the composite coatings prepared with -2 mA has better electrochemical properties. Zirconium dioxide as an intermediate layer improves the bonding between the matrix and the hydroxyapatite coating, and the composite coatings prepared under the process with a current density of -2 mA possess high crystallinity and bonding strength, and their corrosion resistance is superior to both other processes and matrix.

       

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