电沉积铝基FeCoNiCr高熵合金镀层的工艺研究

    Study on Process of Electrodeposited Aluminum-based FeCoNiCr High-entropy Alloy Coating

    • 摘要: 为了在铝合金表面制备一种高导电性和高耐腐蚀性的涂层,采用电沉积技术制备了FeCoNiCr高熵合金镀层。研究了电流密度、镀液pH值、镀液温度和硫酸铬浓度对FeCoNiCr高熵合金镀层表面质量和成分的影响。通过XRD确定了该镀层的物相;通过电化学腐蚀测试和导电性能测试验证了最佳工艺制备的镀层具有高导电性和高耐腐蚀性,最佳工艺为:电流密度3 A/dm2,pH值3,镀液温度25℃,硫酸铬浓度250 g/L。研究发现,FeCoNiCr高熵合金镀层的表面质量和Cr含量相关,当Cr含量最高时,镀层的表面质量最优,镀层表面未见孔洞和裂纹。

       

      Abstract: In order to prepare a high conductivity and corrosion resistance coating on the surface of the aluminum alloy, FeCoNiCr high-entropy alloy coating was prepared by electrodeposition technology. The effects of current density, pH value of the bath, bath temperature and chromium sulfate concentration on the surface quality and composition of the coating were studied. The phase of the coating was determined by XRD. Electrochemical corrosion test and electrical conductivity test verify that the coating prepared through the optimal process exhibits both high conductivity and excellent corrosion resistance. The optimal process parameters are as follows: current density of 3 A/dm2, pH value of 3, bath temperature of 25 ℃, and chromium sulfate concentration of 250 g/L. It is found that the surface quality of the coating is related to Cr content. When Cr content is highest, the surface quality of the coating is best, and no holes and cracks are found on the surface of the coating.

       

    /

    返回文章
    返回